187054
Sigma-Aldrich

4-BROMOBENZYL ALCOHOL, 99

Linear Formula:

BrC6H4CH2OH

Empform:

C7H7BrO

Nacres: NA.22
Mdl No: MFCD00004650
Fw: 187.03
Pubchem Substance Id: 24851248
CAS Number: 873-75-6
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Properties

Properties
assay 99%
Description 4-BROMOBENZYL ALCOHOL, 99
form solid
gene information human ... ALOX12(239) ALOX15(246)
inchi 1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-49H5H2
inchi key VEDDBHYQWFOITD-UHFFFAOYSA-N
Need written commitment NI0000

Description

Application

4-Bromobenzyl alcohol was used in the synthesis of:
  • hydroxyl end functionalized, substituted polyfluorene
  • amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)

General description

4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.

SAFETY INFORMATION

Signal Word

RIDADRRIDADR

WGK Germany

WGK 3

Flash Point (F)

Not applicable

Flash Point (C)

Not applicable

Target Organs

Risk Statement

Supplemental Hazard Statements

DOCUMENTATION

Certificate of Analysis View Sample COA
Certificate of Origin

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